Skip to main content

Two Different Types of Anionic Surfactants

 Anionic surfactant is a kind of product with the longest history, the largest output and the most varieties among surfactants. According to the structure of hydrophilic groups, anionic surfactants can be divided into sulfonates and sulfates, which are the main categories of anionic surfactants. 

 

The anionic surfactants definition is a must-known concept for many people working in the chemical industry. The various functions of surfactants are mainly manifested in changing the properties of the liquid surface, liquid-liquid interface and liquid-solid interface, of which the surface (interface) of the liquid is the most important.

 

Sulfate-type anionic surfactants mainly include fatty alcohol sulfate (also known as primary alkyl sulfate) and secondary alkyl sulfate

1.  Fatty alcohol sulfate (ester) salt (FAS or AS). The general formula of fatty alcohol sulfate is: ROS0-3M+, R is alkyl, M+ is sodium, potassium, ammonium, ethanolamine and other cations, also known as primary alkyl sulfuric acid Salt, English abbreviated as FAS or AS.

 

It is the earliest anionic surfactant after soap. It is prepared by esterification of c12-c14 fatty alcohols generated by Hydrogenolysis of coconut oil with sulfuric acid and neutralization. It has suitable solubility, foaming and decontamination properties. It is widely used in dentifrice, shampoo, bubble bath and cosmetics. It is also an important component in the formulation of light scale, heavy scale detergents, carpet cleaners and hard surface cleaning agents, such as sodium lauryl sulfate (C12H25OSO3Na).

 

2. Secondary alkyl sulfate (Teep01). It is a secondary alkyl sulfate produced by the reaction of olefin and sulfuric acid. It is a product obtained after neutralization. The trade name is Teep01. Teep01, similar to FAS, is also a kind of surfactant agent with good performance, but its solubility and wettability are better due to structural differences. It is usually made into liquid or slurry detergent, since the powder product is easy to absorb moisture and agglomerate.

 

Nanjing Chemical Material Corporation is a professional chemical distributor company which is set up through the restructuring of state-owned Nanjing Chemical Raw Material Head Company. We provide Anionic Surfactant, Cationic Surfactant, DMC Catalyst and so on. Want to know more? Please contact us.



Comments

Popular posts from this blog

Difference Between Sulfate And Sulfonate In Shampoo

  Sulfates and sulfonates have two things in common. First, they're all anionic surfactants. Second, they are often used for personal care applications. But there are many differences. They have different molecular mechanisms. They have different functions and they have different raw materials.   Sulfates Sulfate is a compound. It has carbon bonds and oxygen and sulfur bonds. They include substances such as sodium lauryl sulfate and sodium lauryl ether sulfate.   At low pH, these substances plus the c-o-s bond hydrolyze to produce alcohol and inorganic sulfate. At a high pH, sulfate is stable in the base and, if ethoxylated to a relatively high level, produces a low-foaming alkali-soluble surfactant. Sulphates can be prepared by reaction of fatty alcohol or fatty alcohol ethoxylates with reagents such as SO3 or chlorosulfonic acid (CSA).   The reason shampoo becomes thick foam in the shower is that it contains sulfate. Most shampoos and household cleansers contain su...

How Is Ethyl Bromide Prepared From Ethyl Alcohol 2

  1. Preparation of ethyl bromide  from ethyl alcohol and hydrobromic acid Start with a 1-liter double neck round bottom flask with a drop funnel and wide bend. The bend is connected to a long and efficient condenser assembly and receiver for downward distillation. First, place 281ml (or 415 g) 48% hydrobromic acid in a flask, then add 65ml (or 120 g) of concentrated sulfuric acid in batches, while shaking. As it cools, a small quantity of 145ml (or 100 g) 95% ethanol is slowly added to the mixture of sulfuric acid and hydrobromic acid. Then 109ml (or 200g) of concentrated sulfuric acid is slowly added to the drop funnel, and the ethyl bromine obtained by slow distillation is collected in the cold receiver flask. The crude ethyl bromine was washed with equal volume of concentrated hydrochloric acid, then washed with water and a small amount of 5% sodium bicarbonate solution, then washed with water, and finally dried the ethyl bromine with anhydrous calcium chloride. The crude ...

What is Polyether Polyol

  Polyether polyol is prepared by ring-opening polymerization of epoxide monomers (such as ethylene oxide, propylene oxide and 1,2-epoxybutane) and a compound containing two or more active hydrogen atoms (called an initiator). In the presence of alkali catalyst, active hydrogen compounds initiate ring opening and oxide addition will continue until the required molecular weight is obtained. The number of hydroxyl groups in polyether polyol is determined by the number of unstable hydrogen atoms in the initiator. If the initiator has two active hydrogen, glycol will be formed. The reactivity of polyether polyol  to isocyanates depends on the initiator and the type of epoxy monomer that ends the ring-opening polymerization. The primary hydroxyl produced by polyol capped with ethylene oxide is more reactive than the secondary hydroxyl produced by propylene oxide, which is ideal for applications requiring rapid curing time. However, the use of initiator based on ethylene oxide and a...